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Technology
Assessment & Research (TA&R) Program
| Project Number |
615 |
| Date of Summary |
January 15, 2010 |
| Subject |
Chemical Dispersant Research at Ohmsett |
| Performing Activity |
S.L. Ross Environmental Research Ltd. |
| Principal Investigator |
Mr. Randy Belore, Dr. Ken Trudel, Dr. Alun Lewis |
| Contracting Agency |
Minerals Management Service |
| Estimated Completion |
Completed |
| Description |
The objective of this research program is to continue research and
development on the use of chemical dispersants. The program contains
three separate tasks. Task 1. Calm Seas Application and Dispersant
Wash-Out
The Petroleum Environmental Research Forum (PERF) funded a research
project conducted by SINTEF in Norway and Cedre in France that has
looked at the same issue of dispersant wash out but at laboratory bench
scale. The Oseberg crude oil used in the PERF study was shipped to
Ohmsett and was used in the 2007 study (TAR Project 563). To date no
comparison of the findings from these two studies has been made. The
first item to be addressed in Task 1 will be to complete such a
comparison to determine what can be learned from the different test
methods and scales.
In the testing phase of Task 1 we will implement a similar test
protocol to that used in the spring 2007 testing. Multiple test rings
will be deployed across in the Ohmsett test tank so a range of slick
thickness and/or oil types can be monitored in one test sequence.
Dispersant wash out rates will be monitored throughout the test period
by sampling the surface oil and testing dispersant effectiveness (DE)
using a bench-scale test such as the WSL rotating flask method, as was
done successfully in the 2007 testing, as well as by measuring the
interfacial tension of the sampled oil with fresh sea-water. A two-week
testing program will be conducted May 19-30, 2008 at Ohmsett to test oil
thickness and oil type effects on dispersant wash-out.
Task 2. Surface Wave Energy Characterization for the Ohmsett Test
Tank
The objective of this project would be to measure the surface
turbulence at Ohmsett under various wave configurations and compare
these energies to those encountered in the field at specific sea-states.
There are three basic mixing energies of primary significance in the
dispersion process. These include the process that mixes dispersant into
the oil, the energy that breaks the treated oil into small droplets and
the larger scale energy that mixes the droplets of oil down into the
water column. The proposed work will focus on the quantification of the
surface turbulence available to break the treated slick into a
fine-drop, oil-in-water dispersion. Because of the shallow depth of the
Ohmsett tank the third mixing process cannot be fully simulated at
Ohmsett. The mixing of applied dispersant into the oil versus water is
an important short-term process but it is not the critical component
except where viscous oils or emulsions are involved. A two-week testing
program will be conducted August 18-29, 2008 at Ohmsett.
Task 3. Dispersant Effectiveness on Heavy California Oils
Dispersant effectiveness (DE) experiments were conducted on six
viscous Californian Outer Continental Shelf (OCS) crude oils in April of
2005 at Ohmsett to gather data on this subject. (TAR Project No. 514).
The crude oils tested with viscosities lower than 6500 cP were
dispersible to a significant degree whereas the oils with viscosities of
33,000 cP and greater were not. Oils with similar viscosities yielded
similar DE results suggesting that viscosity alone was a good measure of
likely DE, at least in this test series. Unfortunately oils with
viscosities between 6500 and 33,000 cP were not available for testing
during the 2005 study.
The objective of this project will be to obtain California OCS crude
oils with viscosities between 6,500 and 25,000 cSt and conduct
large-scale experiments at Ohmsett to determine the DE of dispersants in
this viscosity range to fill in the knowledge gap. A one-week testing
program will be conducted June 2-6, 2008 at Ohmsett. |
| Progress |
Task 1. Calm Seas Application and Dispersant Wash-Out
A two-week testing program was successfully conducted May 19-30, 2008 at
Ohmsett to test oil thickness and oil type effects on dispersant wash-out.
The test protocol used was similar to the used in the Spring 2007 calm
seas test series. Multiple test rings were deployed across in the Ohmsett
test tank so a range of slick thickness and/or oil types could be monitored
in one test sequence. Dispersant wash out rates were monitored throughout
the test period by sampling the surface oil and testing dispersant
effectiveness using a bench-scale test such as the WSL rotating flask
method, as was done successfully in the 2007 testing, and by measuring the
interfacial tension of the sampled oil with fresh sea-water. The final
report for this task has been accepted by the MMS and is complete. A peer
reviewed scientific publication is being prepared on the results of this
task.
Task 2. Surface Wave Energy Characterization for the Ohmsett Test Tank
A one-week testing program was successfully conducted August 18-22, 2008
at Ohmsett. The MMS has accepted delivery of the final project report.
Task 3. Dispersant Effectiveness on Heavy California Oils
A one-week DE testing program was successfully conducted June 23-27, 2008
at Ohmsett. The U.S. Coast Guard Atlantic Strike Team, EPA Emergency
Response Team and Clean Islands Council participated in the exercise as an
operational training exercise for the SMART dispersant monitoring protocol.
MMS also conducted a visitor's day on June 25, 2008. Visitors observed
dispersant effectiveness testing, saw the dispersant test protocol in action
and demonstrations of the SMART dispersant monitoring protocol, and toured
the Ohmsett facility. The final report for this task has been accepted by
MMS. This task is complete. A peer reviewed scientific publication is being
prepared on the results of this task. A scientific paper entitled: "Large-Scale Cold Water Dispersant Effectiveness Experiments with Alaskan Crude Oils and Corexit 9500 and 9527 Dispersants" was published in the January 2009 edition of Marine Pollution Bulletin. A scientific paper entitled: "Oil Viscosity Limitation on Dispersibility of Crude Oil Under Simulated At-Sea Conditions In A Large Wave Tank" was published in the February 2010 edition of Marine Pollution Bulletin. |
| Reports |
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AA
(462 KB PDF) |
Dispersant Effectiveness Testing on Viscous U.S. Outer Continental Shelf
Crude Oils: Phase ll, S.L. Ross Environmental Research Ltd., Ottawa, ON,
Canada, 21 pp., November 2008. Ohmsett Test Tank: (Film Clips)
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AB
(1 MB PDF) |
Calm
Seas Application and Dispersant Wash Out" S.L. Ross Environmental Research
Ltd. and A. Lewis Oil Spill Consultancy, Ottawa, ON, Canada, 67 pp.,
December 2008. |
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AC
(2,668 KB PDF) |
Surface Turbulence Measurements at Ohmsett, Febrice Veron, Newark, DE and
S.L. Ross Environmental Research Ltd., Ottawa, ON, Canada 40 pp., April
2009. |
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